The stereodivergent aziridination of allylic carbamates, amides and sulfonamides
Davies SG., Ling KB., Roberts PM., Russell AJ., Thomson JE., Woods PA.
A stereodivergent protocol for the aziridination of a range of cyclic allylic amine derivatives has been developed. syn-Products can be obtained in >99:1 dr under H-bonded control and anti-products are obtained in >99:1 dr under steric control by judicious choice of the N-protecting groups. © 2010 Elsevier Ltd. All rights reserved.